Reef Reference

Reef Chemistry Guide

A complete reference to the parameters that matter in a marine aquarium — what they do, why they matter, and what to do when they drift.

Quick Reference — Natural Seawater Parameters

Parameter Natural Seawater Reef Aquarium Target Unit Importance
pH 8.1 – 8.3 8.1 – 8.3 Critical
Alkalinity 6.5 – 8.5 7 – 11 dKH dKH / meq/L Critical
Calcium ~420 380 – 450 ppm ppm / mg/L Critical
Magnesium ~1285 1250 – 1350 ppm ppm / mg/L Critical
Nitrate (NO₃) < 0.5 1 – 10 ppm ppm / mg/L Important
Phosphate (PO₄) ~0.006 0.05 – 0.1 ppm ppm / mg/L Important
Salinity 1.025 – 1.026 1.025 – 1.026 SG Critical
Temperature 24 – 28 °C 24 – 26 °C °C Critical
Iodine ~0.06 0.04 – 0.08 ppm ppm Beneficial
Strontium ~8 5 – 15 ppm ppm Beneficial
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Alkalinity (kH)

Target: 7 – 11 dKH Natural Seawater: ~8.3 dKH
Pure Reef kH Buffer →

What is it?

Alkalinity (also called carbonate hardness, kH, or dKH) is the measure of carbonate and bicarbonate ions in the water. It acts as the primary pH buffer in a reef aquarium.

Why it matters

Corals and coralline algae consume alkalinity to build their calcium carbonate skeletons. Alkalinity also prevents pH from crashing. It is one of the most rapidly consumed elements in an active reef tank.

⬇ Too Low

  • Coral stress and bleaching
  • pH crashes, especially at night
  • Dying off of coral in severe cases
  • Stalled coral growth

⬆ Too High

  • Calcium precipitation
  • Cloudiness
  • Inhibition of coral growth at extreme levels
💡 Pro Tip: Test alkalinity every 2–3 days in an active reef. Consistent levels are more important than hitting a perfect number — avoid swings of more than 0.5 dKH per day.
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Calcium

Target: 380 – 450 ppm Natural Seawater: ~420 ppm
Pure Reef Calcium →

What is it?

Calcium is one of the major ions in seawater and one of the primary building blocks of coral skeletons, shells, and coralline algae.

Why it matters

Corals, clams, urchins, and coralline algae all require calcium to build their calcium carbonate structures. In a well-stocked reef, calcium can drop significantly each day.

⬇ Too Low

  • Weak, brittle skeletons in SPS and LPS corals
  • Slowed coral growth
  • Organisms become stressed
  • Mortality in severe cases

⬆ Too High

  • Calcium precipitation with alkalinity
  • Cloudiness and white deposits on equipment
💡 Pro Tip: Calcium and alkalinity are chemically linked — you cannot raise one significantly without monitoring the other. Aim for a balanced approach.
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Magnesium

Target: 1250 – 1350 ppm Natural Seawater: ~1285 ppm
Pure Reef Magnesium →

What is it?

Magnesium is the third most abundant ion in seawater. It plays a critical role in preventing spontaneous precipitation of calcium carbonate, which keeps calcium and alkalinity stable.

Why it matters

Low magnesium is often the hidden cause of calcium and alkalinity problems. Without adequate magnesium, even correct calcium and alkalinity dosing cannot stabilise tank chemistry.

⬇ Too Low

  • Inability to maintain calcium and alkalinity levels
  • Calcium carbonate precipitation on heaters and pumps
  • White deposits on aquarium glass
  • Inhibited coral growth

⬆ Too High

  • Sedation of fish and invertebrates at extreme levels (above 1800 ppm)
  • Generally not a concern with normal maintenance dosing
💡 Pro Tip: If you are struggling to maintain calcium or alkalinity levels despite dosing, test magnesium first. Low magnesium is the most common cause of unstable reef chemistry.
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Phosphate (PO₄)

Target: 0.05 – 0.1 ppm Natural Seawater: ~0.006 ppm (NSW)
Pure Reef Phosphate Remover / Phosphate Plus →

What is it?

Phosphate is a nutrient that accumulates from fish waste, uneaten food, and decomposition. While NSW has very low phosphate, reef aquaria benefit from a small amount for coral metabolism.

Why it matters

Phosphate at zero starves corals and causes bleaching. However, excess phosphate fuels nuisance algae growth that competes with corals and inhibits skeleton formation.

⬇ Too Low

  • Coral tissue recession
  • Fading and bleaching of coral colouration
  • Slowed growth

⬆ Too High

  • Rapid algae growth (hair algae, cyanobacteria)
  • Inhibited coral calcification
  • Fading coral colours
💡 Pro Tip: Phosphate and nitrate work together — maintain a ratio of approximately 1:16 (PO₄:NO₃) to keep the system balanced and coral colours vibrant.
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Nitrate (NO₃)

Target: 1 – 10 ppm Natural Seawater: ~0.2 ppm (NSW)
Pure Reef Nitrate Plus →

What is it?

Nitrate is the end product of the nitrogen cycle in an aquarium, produced as bacteria break down ammonia and nitrite. Unlike fish-only systems, reef aquaria need some nitrate.

Why it matters

Zooxanthellae (the symbiotic algae inside coral tissue) require nitrogen for photosynthesis. Zero nitrate starves coral tissue and causes bleaching.

⬇ Too Low

  • Coral bleaching
  • Loss of zooxanthellae
  • Pale coral colouration
  • Slow growth

⬆ Too High

  • Algae blooms
  • Stress to sensitive SPS corals
  • Reduced colouration
  • Elevated phosphate
💡 Pro Tip: Ultra-low nutrient systems (ULNS) can strip nitrate below safe levels. If you run heavy skimming, carbon dosing, or a refugium, test nitrate weekly.

Trace Elements

Target: Natural seawater ratios Natural Seawater: 82 trace elements
Pure Reef Trace Elements →

What is it?

Natural seawater contains 82 elements at trace concentrations. The most important for reef aquaria include iodine, strontium, potassium, iron, molybdenum, and manganese.

Why it matters

Trace elements are removed by protein skimming, activated carbon, and the biological processes of corals and invertebrates. Regular replenishment maintains the vibrant colouration and health of reef inhabitants.

⬇ Too Low

  • Muted or faded coral colouration
  • Reduced polyp extension
  • Slow growth of SPS corals
  • Weakened immune response

⬆ Too High

  • Toxicity at extreme doses
  • Generally safe with label dosing
💡 Pro Tip: If you do 10% water changes weekly with a quality reef salt, trace elements may be adequately replenished. In tanks with lower water change frequency, regular dosing becomes important.